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Guide to Lithium Batteries

Lithium Batterie : What is it?

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A lithium battery is a primary battery that uses lithium as anode. It is lightweight and a good conductor. It also has a high electrochemical equivalence and voltage. It produces about twice the voltage of an alkaline cell or a zinc-carbon battery. It is used in a wide variety of applications such as in consumer electronics, digital devices, electronic medical devices, industrial applications, toys, back-up batteries in computers and communication devices, and security systems. The average lifetime of a rechargeable lithium battery is approximately seven to 10 years.

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Types Of Lithium Batteries

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Kinds of Lithium Batteries include the following:

Manganese oxide ( Li-MnO2 (Li-Mn, "CR") )

  • Manganese oxide batteries comprise about 80% of the lithium battery market.
  • They are suitable for low-cost, low-drain, long-life applications.
  • They have high densities per mass and volume and deliver high pulse currents.


Thionyl chloride (Li-SOCl2)

  • Thionyl chloride batteries are liquid cathodes used in low temperature applications with toxic elements.
  • They can operate at -55 degrees Celsius while retaining more than 50% of their rated capacities.
  • The low-current cells are used for memory backup and portable electronics, while the high-current cells are used in military applications.


Sulfuryl chloride (Li-SO2Cl2)

  • Sulfuryl chloride batteries are liquid cathodes similar to thionyl chloride.
  • However, their discharge do not build up into elemental sulfur, making them safer to use.
  • They give less maximum current than thionyl chloride because of the polarization of the carbon cathode.


Sulfur dioxide on teflon-bonded carbon (Li-SO2)

  • Sulfur dioxide on teflon-bonded carbon batteries can operate at -55 degrees Celsius up to 70 degrees Celsius.
  • They require safety vents because they can explode in some conditions.
  • They are used in military applications.


Carbon monoflouride ( Li-(CF)x ("BR") )


  • Carbon monoflouride batteries are cathode materials formed by the high temperature intercalation of fluorine gas into graphite powder.
  • They are used in low to moderate applications such as clock backup batteries and memory.
  • They have a good safety record.
  • They are also used in aerospace, marine, and terrestrial applications.


Iodine (Li-I2)


  • Iodine batteries are solid electrolytes that do not generate gas even under short circuit conditions.
  • They are highly reliable.
  • They have a solid-state chemistry and limited chort-circuit currents.
  • They are used in medical applications.


Silver chromate (Li-Ag2CrO4)

  • Silver chromate batteries are developed specifically for medical applications such as for implanted pacemakers.


Silver oxide+vanadium pentoxide (Li-Ag2V4O11, Li-SVO, Li-CSVO)


  • Silver oxide+vanadium pentoxide batteries are designed for medical applications such as in neurostimulators, implantable defibrillators, and drug infusion systems.
  • They are also used in other electronic applications such as in emergency locator transmitters.


Iron Sulfide (Li-FeS)

  • Also referred to as Lithium-iron batteries, iron sulfide batteries are used as replacements for alkaline batteries.
  • They are used for domestic applications.
  • One of their variants is iron disulfide batteries.


Lead bismushate (Li-Bi2Pb2O5)


  • Lead bismushate batteries are used as replacements for silver oxide batteries.
  • They have higher energy densities.
  • They perform better at higher temperatures.
  • They have a lower tendency to leak.


Rechargeable lithium batteries

  • Rechargeable lithium batteries include cobalt dioxide, copper chloride, manganese dioxide, Vanadium pntoxide, carbon, and ploymer batteries.

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Choosing Lithium Batteries (Buying Tips)

Environment friendliness:  Choose a lithium battery with the least impact on the environment, in the manufacturing process, use, and disposal. Its toxic effect does not only affect the environment, but human health as well.

Safety standards:
  Only choose a lithium battery that has been tested and approved by an international or a national safety standards organization. Do not purchase counterfeit or generic lithium batteries.

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Sources

Panasonic
Wikipedia
FSU

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